磷酸铥
磷酸铥 是一种无机化合物 ,化学式为TmPO4 。它的二水合物可由氯化铥 和磷酸钠 在水溶液中反应得到,加热二水合物可以得到无水物。[1] 它的无水单晶也可由磷酸二氢铵 和氧化铥 在氧化铅 -五氧化二磷 (1:1)熔体中反应,生长得到。[2] 它和氟化钠 反应,可以得到Na3 Tm2 F3 PO4 。[3]
参考文献
^ Kalieva, K.; Stretkova, Z. V.; Babynina, N. A.; Gordienko, L. N.; Votoyarov, M.; Yakimov; Sakavov, I. E.; Mustaev, A. K. X-ray diffraction studies of praseodymium, neodymium, europium, terbium, dysprosium, erbium, holmium, and terbium orthophosphates. Tr. Kirg. Univ., Ser. Khim. Nauk , 1972. 2: 84-89.
^ O Gomis, B Lavina, P Rodríguez-Hernández, A Muñoz, R Errandonea, D Errandonea, M Bettinelli. High-pressure structural, elastic, and thermodynamic properties of zircon-type HoPO 4 and TmPO 4 . Journal of Physics: Condensed Matter. 2017-03-08, 29 (9): 095401 [2022-06-25 ] . ISSN 0953-8984 . doi:10.1088/1361-648X/aa516a .
^ Smirnova, I.N.; Gorkovenko, M.Yu.; Zimina, G.V.; Spiridonov, F.M.; Kaloev, N.I.; Komissarova, L.N. Rare earth fluorophosphates. Izvestiya Vysshikh Uchebnykh Zavedenii, Tsvetnaya Metallurgiya , 1994. 1-2: 71-74.
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