Cerium
Cerium, 58 Ce Cerium Pronunciation (SEER -ee-əm ) Appearance sillery white Standard atomic weight A r, std (Ce) 7002140116000000000♠ 140.116(1)[1] Cerium in the periodic cairt
Atomic nummer (Z ) 58 Group group n/a Period period 6 Block f-block Element category Lanthanide Electron confeeguration [Xe ] 4f1 5d1 6s2 [2] Electrons per shell 2, 8, 18, 19, 9, 2 Pheesical properties Phase at STP solit Meltin pynt 1068 K (795 °C, 1463 °F) Bylin pynt 3716 K (3443 °C, 6229 °F) Density (near r.t. ) 6.770 g/cm3 when liquid (at m.p. ) 6.55 g/cm3 Heat o fusion 5.46 kJ/mol Heat o vapourisation 398 kJ/mol Molar heat capacity 26.94 J/(mol·K) Vapour pressur
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1992
2194
2442
2754
3159
3705
Atomic properties Oxidation states +1, +2, +3 , +4 (a mildly basic oxide) Electronegativity Pauling scale: 1.12 Atomic radius empirical: 181.8 pm Covalent radius 204±9 pm Colour lines in a spectral range Spectral lines o cerium Ither properties Naitural occurrence primordial Creestal structur face-centred cubic (fcc) Speed o soond thin rod 2100 m/s (at 20 °C) Thermal expansion (r.t.) (γ, poly) 6.3 µm/(m·K) Thermal conductivity 11.3 W/(m·K) Electrical resistivity (r.t.) (β, poly) 828 n Ω·m Magnetic orderin paramagnetic[3] Young's modulus (γ form) 33.6 GPa Shear modulus (γ form) 13.5 GPa Bulk modulus (γ form) 21.5 GPa Poisson ratio (γ form) 0.24 Mohs haurdness 2.5 Vickers haurdness 270 MPa Brinell haurdness 412 MPa CAS Nummer 7440-45-1 History Namin efter dwarf planet Ceres , itsel named efter Roman deity o agricultur Ceres Diskivery Martin Heinrich Klaproth, Jöns Jakob Berzelius, Wilhelm Hisinger (1803) First isolation Carl Gustaf Mosander (1839) Main isotopes o cerium
Isotope
Abundance
Hauf-life (t 1/2 )
Decay mode
Product
134 Ce
syn
3.16 d
ε
134La
136 Ce
0.185%
>3.8×1016 y
(β+β+)
136Ba
138 Ce
0.251%
>1.5×1014 y
(β+β+)
138Ba
139 Ce
syn
137.640 d
ε
139La
140 Ce
88.450%
-
(SF)
141 Ce
syn
32.501 d
β−
141Pr
142 Ce
11.114%
>5×1016 y
(β−β−)
142Nd
(α)
138Ba
144 Ce
syn
284.893 d
β−
144Pr
Decay modes in parentheses is predict, but hisna yet been observed | references
Cerium is a chemical element wi seembol Ce an atomic nummer 58. It is a saft, silvery, ductile metal which easily oxidizes in air. Cerium wis named efter the dwarf planet Ceres (itsel named for the Roman goddess o agricultur). Cerium is the maist abundant o the rare yird elements, makin up aboot 0.0046% o the Yird's crust bi wicht. It is foond in a feck o minerals, the maist important bein monazite an bastnasite. Thare a wheen o ommercial applications o cerium. Thay include catalysts, additives fur tae fuel tae reduce emissions an tae gless an enamels tae chynge thair colour. Cerium oxide is an important component o gless polishin pouders an phosphors uised in screens an fluorescent lamps. It is uised in the "flint" (actually ferrocerium) o lichters.
References
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